Document Detail

Guest-Cage Atomic Interactions in a Clathrate-based Phase-Change Material.
MedLine Citation:
PMID:  24375618     Owner:  NLM     Status:  Publisher    
We report new clathrate-based phase-change materials with cage-like structures incorporating Cs and Ba guest atoms, as a means of altering crystallization and amorphization behaviour by controlling 'guest-cage' interactions via intra-complex guest vibrational effects. Both a high resistance to spontaneous crystallization, and long retention of the amorphous phase were achieved, as well as a low melting energy. This approach provides a route for achieving cage-controlled semiconductor devices.
Desmond Loke; Jonathan M Skelton; Leong-Tat Law; Wei-Jie Wang; Ming-Hua Li; Wen-Dong Song; Tae-Hoon Lee; Stephen R Elliott
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-12-23
Journal Detail:
Title:  Advanced materials (Deerfield Beach, Fla.)     Volume:  -     ISSN:  1521-4095     ISO Abbreviation:  Adv. Mater. Weinheim     Publication Date:  2013 Dec 
Date Detail:
Created Date:  2013-12-30     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9885358     Medline TA:  Adv Mater     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
© 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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