Document Detail


Gradient Isotactic Multiblock Polylactides from Aluminum Complexes of Chiral Salalen Ligands.
MedLine Citation:
PMID:  24521164     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Aluminum complexes of enantiomerically-pure aminomethylpyrrolidine-based salalen ligands and their applica-tion in the stereoselective polymerization of lactide are described. Poly(lactic acid) featuring the new gradient isotactic multiblock microstructure was synthesized by isoselective catalysts which operate by a combination of enantiomorphic-site and chain-end control mechanisms.
Authors:
Alessia Pilone; Konstantin Press; Israel Goldberg; Moshe Kol; Mina Mazzeo; Marina Lamberti
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2014-2-12
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  -     ISSN:  1520-5126     ISO Abbreviation:  J. Am. Chem. Soc.     Publication Date:  2014 Feb 
Date Detail:
Created Date:  2014-2-13     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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