| Gold(I) triphenylphosphine complexes incorporating pentaarylfulleride ligands. | |
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MedLine Citation:
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PMID: 20377195 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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Two gold(I) complexes, (Ph(3)P)Au[C(60)(4-MeC(6)H(4))(5)] (1) and (Ph(3)P)Au[C(60)(4-t-BuC(6)H(4))(5)] (2), were prepared in excellent yield and characterized by single-crystal X-ray diffraction. Complex 1, grown from two solvent systems, has different coordination modes of the fullerene-embedded Cp ring to the (PPh(3))Au fragment. For 1.(ODCB)(2), the cyclopentadienyl ring coordinates to the (Ph(3)P)Au fragment in an eta(1) fashion distorted toward eta(3) geometry, while in 1.(CHCl(3))(2)(CS(2)), crystal packing forces produce enough distortion to give near eta(2) coordination. |
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Authors:
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Merissa Halim; Robert D Kennedy; Saeed I Khan; Yves Rubin |
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Publication Detail:
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Type: Journal Article; Research Support, U.S. Gov't, Non-P.H.S. |
Journal Detail:
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Title: Inorganic chemistry Volume: 49 ISSN: 1520-510X ISO Abbreviation: Inorg Chem Publication Date: 2010 May |
Date Detail:
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Created Date: 2010-04-26 Completed Date: 2010-07-19 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0366543 Medline TA: Inorg Chem Country: United States |
Other Details:
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Languages: eng Pagination: 3974-6 Citation Subset: IM |
Affiliation:
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Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569, USA. |
Export Citation:
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APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
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Crystallography, X-Ray Fullerenes / chemistry* Gold / chemistry* Ligands Models, Molecular Organogold Compounds / chemical synthesis*, chemistry* Organophosphorus Compounds / chemistry* |
| Chemical | |
Reg. No./Substance:
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0/Fullerenes; 0/Ligands; 0/Organogold Compounds; 0/Organophosphorus Compounds; 603-35-0/triphenylphosphine; 7440-57-5/Gold; 99685-96-8/fullerene C60 |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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