Document Detail

Gold(I) triphenylphosphine complexes incorporating pentaarylfulleride ligands.
MedLine Citation:
PMID:  20377195     Owner:  NLM     Status:  MEDLINE    
Two gold(I) complexes, (Ph(3)P)Au[C(60)(4-MeC(6)H(4))(5)] (1) and (Ph(3)P)Au[C(60)(4-t-BuC(6)H(4))(5)] (2), were prepared in excellent yield and characterized by single-crystal X-ray diffraction. Complex 1, grown from two solvent systems, has different coordination modes of the fullerene-embedded Cp ring to the (PPh(3))Au fragment. For 1.(ODCB)(2), the cyclopentadienyl ring coordinates to the (Ph(3)P)Au fragment in an eta(1) fashion distorted toward eta(3) geometry, while in 1.(CHCl(3))(2)(CS(2)), crystal packing forces produce enough distortion to give near eta(2) coordination.
Merissa Halim; Robert D Kennedy; Saeed I Khan; Yves Rubin
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Publication Detail:
Type:  Journal Article; Research Support, U.S. Gov't, Non-P.H.S.    
Journal Detail:
Title:  Inorganic chemistry     Volume:  49     ISSN:  1520-510X     ISO Abbreviation:  Inorg Chem     Publication Date:  2010 May 
Date Detail:
Created Date:  2010-04-26     Completed Date:  2010-07-19     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0366543     Medline TA:  Inorg Chem     Country:  United States    
Other Details:
Languages:  eng     Pagination:  3974-6     Citation Subset:  IM    
Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569, USA.
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MeSH Terms
Crystallography, X-Ray
Fullerenes / chemistry*
Gold / chemistry*
Models, Molecular
Organogold Compounds / chemical synthesis*,  chemistry*
Organophosphorus Compounds / chemistry*
Reg. No./Substance:
0/Fullerenes; 0/Ligands; 0/Organogold Compounds; 0/Organophosphorus Compounds; 603-35-0/triphenylphosphine; 7440-57-5/Gold; 99685-96-8/fullerene C60

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