| Glycoluril dimer isomerization under aqueous acidic conditions related to cucurbituril formation. | |
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MedLine Citation:
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PMID: 23151064 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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A water-soluble methylene-bridged glycoluril dimer 2S was isolated. It was shown that 2S is only kinetic product of the reaction between glycoluril derivative 1 and paraformaldehyde. 2S is subsequently intermolecularly transformed into its diastereomer 2C. The kinetics and thermodynamics of the S- to C-shaped dimer isomerization were investigated under reaction conditions similar to cucurbituril synthesis. |
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Authors:
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Marek Stancl; Zuzana Gargulakova; Vladimir Sindelar |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-11-14 |
Journal Detail:
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Title: The Journal of organic chemistry Volume: - ISSN: 1520-6904 ISO Abbreviation: J. Org. Chem. Publication Date: 2012 Nov |
Date Detail:
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Created Date: 2012-11-15 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 2985193R Medline TA: J Org Chem Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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