Document Detail


Glycoluril dimer isomerization under aqueous acidic conditions related to cucurbituril formation.
MedLine Citation:
PMID:  23151064     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
A water-soluble methylene-bridged glycoluril dimer 2S was isolated. It was shown that 2S is only kinetic product of the reaction between glycoluril derivative 1 and paraformaldehyde. 2S is subsequently intermolecularly transformed into its diastereomer 2C. The kinetics and thermodynamics of the S- to C-shaped dimer isomerization were investigated under reaction conditions similar to cucurbituril synthesis.
Authors:
Marek Stancl; Zuzana Gargulakova; Vladimir Sindelar
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-14
Journal Detail:
Title:  The Journal of organic chemistry     Volume:  -     ISSN:  1520-6904     ISO Abbreviation:  J. Org. Chem.     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-15     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2985193R     Medline TA:  J Org Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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