Document Detail


Global source-receptor relationships for mercury deposition under present-day and 2050 emissions scenarios.
MedLine Citation:
PMID:  22050654     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Global policies regulating anthropogenic mercury require an understanding of the relationship between emitted and deposited mercury on intercontinental scales. Here, we examine source-receptor relationships for present-day conditions and four 2050 IPCC scenarios encompassing a range of economic development and environmental regulation projections. We use the GEOS-Chem global model to track mercury from its point of emission through rapid cycling in surface ocean and land reservoirs to its accumulation in longer lived ocean and soil pools. Deposited mercury has a local component (emitted Hg(II), lifetime of 3.7 days against deposition) and a global component (emitted Hg(0), lifetime of 6 months against deposition). Fast recycling of deposited mercury through photoreduction of Hg(II) and re-emission of Hg(0) from surface reservoirs (ice, land, surface ocean) increases the effective lifetime of anthropogenic mercury to 9 months against loss to legacy reservoirs (soil pools and the subsurface ocean). This lifetime is still sufficiently short that source-receptor relationships have a strong hemispheric signature. Asian emissions are the largest source of anthropogenic deposition to all ocean basins, though there is also regional source influence from upwind continents. Current anthropogenic emissions account for only about one-third of mercury deposition to the global ocean with the remainder from natural and legacy sources. However, controls on anthropogenic emissions would have the added benefit of reducing the legacy mercury re-emitted to the atmosphere. Better understanding is needed of the time scales for transfer of mercury from active pools to stable geochemical reservoirs.
Authors:
Elizabeth S Corbitt; Daniel J Jacob; Christopher D Holmes; David G Streets; Elsie M Sunderland
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Publication Detail:
Type:  Journal Article; Research Support, N.I.H., Extramural; Research Support, Non-U.S. Gov't; Research Support, U.S. Gov't, Non-P.H.S.     Date:  2011-11-18
Journal Detail:
Title:  Environmental science & technology     Volume:  45     ISSN:  1520-5851     ISO Abbreviation:  Environ. Sci. Technol.     Publication Date:  2011 Dec 
Date Detail:
Created Date:  2011-12-23     Completed Date:  2012-04-09     Revised Date:  2013-02-20    
Medline Journal Info:
Nlm Unique ID:  0213155     Medline TA:  Environ Sci Technol     Country:  United States    
Other Details:
Languages:  eng     Pagination:  10477-84     Citation Subset:  IM    
Affiliation:
Department of Earth and Planetary Sciences, Harvard University, Cambridge, Massachusetts 02138, United States. corbitt@seas.harvard.edu
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MeSH Terms
Descriptor/Qualifier:
Environmental Monitoring / methods*
Environmental Pollutants / analysis*
Environmental Pollution / statistics & numerical data*
Mercury / analysis*
Models, Chemical
Statistics as Topic
Grant Support
ID/Acronym/Agency:
P30 ES000002/ES/NIEHS NIH HHS; P30 ES000002-45/ES/NIEHS NIH HHS
Chemical
Reg. No./Substance:
0/Environmental Pollutants; 7439-97-6/Mercury
Comments/Corrections

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