Document Detail


Generation of benzyne from benzoic acid using C-H activation.
MedLine Citation:
PMID:  20957240     Owner:  NLM     Status:  In-Process    
Abstract/OtherAbstract:
ortho C-H activation of benzoic acids with Pd(II) generates an oxapalladacycle that can decarboxylate to produce a palladium-associated aryne. The arynes then undergo [2+2+2] trimerisation to afford triphenylenes.
Authors:
Alastair A Cant; Lee Roberts; Michael F Greaney
Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't     Date:  2010-10-18
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  46     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2010 Dec 
Date Detail:
Created Date:  2010-11-10     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  England    
Other Details:
Languages:  eng     Pagination:  8671-3     Citation Subset:  IM    
Affiliation:
School of Chemistry, University of Edinburgh, King's Buildings, West Mains Rd, Edinburgh, UK.
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MeSH Terms
Descriptor/Qualifier:
Grant Support
ID/Acronym/Agency:
//Cancer Research UK

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