| General and functional group-tolerable approach to allenylsilanes by rhodium-catalyzed coupling between propargylic carbonates and a silylboronate. | |
| | |
MedLine Citation:
|
PMID: 19908884 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
|
The Rh-catalyzed coupling reaction between propargylic carbonates and a silylboronate afforded allenylsilanes with different substitution patterns in high yields. The reaction tolerates a variety of functional groups in propargylic carbonates. The reaction of an optically active propargylic carbonate proceeded with excellent chirality transfer with 1,3-anti stereochemistry to give an axially chiral allenylsilane. |
| | |
Authors:
|
Hirohisa Ohmiya; Hideto Ito; Masaya Sawamura |
Related Documents
:
|
20013994 - Synthesis of n-arylated 1,2-dihydroheteroaromatics through the three-component reaction... 19641784 - The [3 + 2] cycloaddition reaction of thiazole carbene-derived c-c-se 1,3-dipoles: a co... 17455944 - Tandem gold(i)-catalyzed cyclization/electrophilic cyclopropanation of vinyl allenes. 20687594 - Pd-catalyzed assembly of spirooxindole natural products: a short synthesis of horsfiline. 19740694 - Ultrasound promoted synthesis of thioesters from 2-mercaptobenzoxa(thia)zoles. 19398344 - Synthesis and antirhinovirus activity of new 3-benzyl chromene and chroman derivatives. |
Publication Detail:
|
Type: Journal Article |
Journal Detail:
|
Title: Organic letters Volume: 11 ISSN: 1523-7052 ISO Abbreviation: Org. Lett. Publication Date: 2009 Dec |
Date Detail:
|
Created Date: 2009-12-16 Completed Date: 2010-02-02 Revised Date: - |
Medline Journal Info:
|
Nlm Unique ID: 100890393 Medline TA: Org Lett Country: United States |
Other Details:
|
Languages: eng Pagination: 5618-20 Citation Subset: - |
Affiliation:
|
Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan. |
Export Citation:
|
APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
|
|
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
Previous Document: Carbonyldiimidazole-Mediated Lossen Rearrangement.
Next Document: Ambient Temperature Hydrophosphination of Internal, Unactivated Alkynes and Allenyl Phosphineoxides ...