| A general approach to anionic acid-labile surfactants with tunable properties. | |
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MedLine Citation:
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PMID: 20726615 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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A general approach to the synthesis of a new series of unique sulfate anionic acid-labile surfactants (AALS) was developed. In this approach, the ketal was derived from methyl pyruvate, and the sulfate motif was introduced via sulfitylation of the alcohol, oxidation, and finally conversion of the sulfate diester to the desired sodium salt. The physicochemical properties in aqueous solution of this novel series of surfactants, such as CMCs, solubility, acid lability, and stability were studied. |
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Authors:
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Miaosheng Li; Matthew J Powell; Trust T Razunguzwa; George A O'Doherty |
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Publication Detail:
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Type: Journal Article |
Journal Detail:
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Title: The Journal of organic chemistry Volume: 75 ISSN: 1520-6904 ISO Abbreviation: J. Org. Chem. Publication Date: 2010 Sep |
Date Detail:
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Created Date: 2010-09-10 Completed Date: 2011-01-11 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 2985193R Medline TA: J Org Chem Country: United States |
Other Details:
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Languages: eng Pagination: 6149-53 Citation Subset: IM |
Affiliation:
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Protea Biosciences, 955 Hartman Run Road, Morgantown, West Virginia 26507, USA. miaosheng·li@proteabio.com |
Export Citation:
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APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
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Anions
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chemistry Molecular Structure Stereoisomerism Sulfuric Acids / chemistry* Surface-Active Agents / chemical synthesis*, chemistry |
| Chemical | |
Reg. No./Substance:
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0/Anions; 0/Sulfuric Acids; 0/Surface-Active Agents; 7664-93-9/sulfuric acid |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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