Document Detail


Geminally Diaurated Gold(I) Aryls from Boronic Acids.
MedLine Citation:
PMID:  22565395     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The electrophilic [Ph(3) PAu]NTf(2) quickly diaurates aryl boronic acids providing stable geminally diaurated complexes (see example; yellow, Au; orange, P; blue, C) that have been spectroscopically, and in some cases crystallographically, characterized. Geminally diaurated arenes are putative intermediates in gold(I) catalysis and are analogues of Wheland intermediates of electrophilic aromatic substitutions.
Authors:
James E Heckler; Matthias Zeller; Allen D Hunter; Thomas G Gray
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-5-4
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  -     ISSN:  1521-3773     ISO Abbreviation:  -     Publication Date:  2012 May 
Date Detail:
Created Date:  2012-5-8     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Department of Chemistry, Case Western Reserve University, Cleveland, OH 44106 (USA) http://gray.case.edu/
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