Document Detail


[Ge(12) {FeCp(CO)(2) }(8) {FeCp(CO)}(2) ]: A Ge(12) Core Resembles the Arrangement of the High-Pressure Modification Germanium (II).
MedLine Citation:
PMID:  23288682     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Similar yet different: The reaction of a GeBr solution with K[FeCp(CO)(2) ] (Cp=η-C(5) H(5) ) gives [Ge(12) {FeCp(CO)(2) }(8) {FeCp(CO)}(2) ] (1), whose oblong, highly cross-linked cluster core reveals a cut-out of the high-pressure solid-state structure of germanium (II). Mass spectrometric investigations on the gas-phase species [Ge(6) {FeCp(CO)(2) }(6) {FeCp(CO)}](-) (2) and theoretical calculations on 1 and 2 illuminate the formation of the metalloid cluster 1.
Authors:
Christian Schenk; Florian Henke; Andreas Schnepf
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-3
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  -     ISSN:  1521-3773     ISO Abbreviation:  Angew. Chem. Int. Ed. Engl.     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-4     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Institut für Allgemeine und Anorganische Chemie, Universität Heidelberg, Im Neuenheimer Feld 270,69120 Heidelberg (Germany).
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