Document Detail


Gas phase charged aggregates of bis(2-ethylhexyl)sulfosuccinate (AOT) and divalent metal ions: first evidence of AOT solvated aggregates.
MedLine Citation:
PMID:  21915957     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
Assembling and chelating properties of sodium bis(2-ethylhexyl)sulfosuccinate (AOTNa) towards divalent metal ions have been investigated in the gas phase by electrospray ionization mass spectrometry. A variety of positively charged monometallated and mixed metal aggregates are formed. Interestingly, several ions contain solvent (MeOH, H(2) O) molecules and constitute the most abundant AOT cationic aggregates not containing sodium. These species are the first example of solvated AOT-metal ion aggregates in the gas phase. By increasing the surfactant aggregation number, the abundance of solvated species becomes lower than that of unsolvated ones. Decompositions of ionic species have been studied by tandem mass spectrometry, and their stability has been determined through energy resolved mass spectrometry. In contrast with positively charged AOT-alkaline metal ion aggregates, whose decompositions are dominated by the loss of individual surfactant molecules, AOTNa-divalent ion aggregates mainly dissociate through the cleavage of the AOT H(2) C-O bond followed by further intramolecular fragmentations. This finding, that is consistent with an enhanced chelation of divalent ions with AOT(-) head groups, has been taken as an indication that such aggregates are characterized by a reverse micelle-like organization with a ionic core formed by the metal cations interacting with the negatively charged surfactant polar heads, whereas the surfactant alkyl chains point outside. Copyright © 2011 John Wiley & Sons, Ltd.
Authors:
Gianluca Giorgi; Ivana Pini; Leopoldo Ceraulo; Vincenzo Turco Liveri
Related Documents :
22101707 - Biomolecule/nanomaterial hybrid systems for nanobiotechnology.
21852497 - A main group metal sandwich: five lithium cations jammed between two corannulene tetraa...
22294477 - Morphologies and elemental compositions of calcium crystals in phyllodes and branchlets...
21693917 - Probing hydrogen interactions with amorphous metals using first-principles calculations.
8889187 - Monomer concentrations and dimerization constants in crystallizing lysozyme solutions b...
16575937 - Enantio- and diastereoselective michael addition reactions of unmodified aldehydes and ...
Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Journal of mass spectrometry : JMS     Volume:  46     ISSN:  1096-9888     ISO Abbreviation:  J Mass Spectrom     Publication Date:  2011 Sep 
Date Detail:
Created Date:  2011-09-14     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9504818     Medline TA:  J Mass Spectrom     Country:  England    
Other Details:
Languages:  eng     Pagination:  925-32     Citation Subset:  IM    
Copyright Information:
Copyright © 2011 John Wiley & Sons, Ltd.
Affiliation:
Dipartimento di Chimica, Università degli Studi di Siena, Via Aldo Moro, I-53100, Siena, Italy. gianluca.giorgi@unisi.it.
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


Previous Document:  An isomer-specific high-energy collision-induced dissociation MS/MS database for forensic applicatio...
Next Document:  How to distinguish between cinnamoylshikimate esters and chlorogenic acid lactones by liquid chromat...