Document Detail

Gas chromatography of uracil herbicides by on-column methylation with trimethylanilinium hydroxide.
MedLine Citation:
PMID:  3771467     Owner:  NLM     Status:  MEDLINE    
Substituted uracil herbicides injected into a gas chromatograph react with trimethylanilinium hydroxide to give N-methyl derivatives with good gas chromatographic properties. Maximum methylation is obtained when the molar ratio of methylating reagent to herbicide is ca 4:1. This technique for preparing derivatives provides rapid qualitative and quantitative chromatography of the substances examined. Chromatographic response was linear with increased concentration for the synthetic standard and the on-column product of uracil herbicide. The proposed derivatization method was used to analyze herbicides in formulations. The methyl derivatives were identified spectroscopically.
L Ogierman
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Journal - Association of Official Analytical Chemists     Volume:  69     ISSN:  0004-5756     ISO Abbreviation:  J Assoc Off Anal Chem     Publication Date:    1986 Sep-Oct
Date Detail:
Created Date:  1986-12-17     Completed Date:  1986-12-17     Revised Date:  2006-11-15    
Medline Journal Info:
Nlm Unique ID:  7505559     Medline TA:  J Assoc Off Anal Chem     Country:  UNITED STATES    
Other Details:
Languages:  eng     Pagination:  912-4     Citation Subset:  IM    
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MeSH Terms
Chromatography, Gas / methods
Gas Chromatography-Mass Spectrometry / methods
Herbicides / analysis*
Quaternary Ammonium Compounds
Uracil / analogs & derivatives*
Reg. No./Substance:
0/Herbicides; 0/Quaternary Ammonium Compounds; 3426-74-2/phenyltrimethylammonium; 66-22-8/Uracil

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine

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