Document Detail


Gas chromatographic determination of thiabendazole in fruits as its methyl derivative.
MedLine Citation:
PMID:  1249146     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Quantitative determination of thiabendazole, as its methyl derivative, has been achieved by gas-liquid chromatography with flame ionization detection and a column of 10% of DC-200 on Gas-Chrom Q at 240 degrees. Determination was possible with 10 to 200 ng per mul of the methylated reaction mixture. For determining thiabendazole in fruits, clean-up of the crude extracts by liquid-liquid partition allows satisfactory elimination of interference and permits determination in concentrations down to 0.1 ppm. The recovery of thiabendazole added to fruits at the 0.5-ppm level ranges from 90.3 to 94.9%. The methyl derivative was identified as N-methylthiabendazole by its elementary composition, by its melting-point, and by ultraviolet, infrared, mass and nuclear magnetic resonance spectroscopy.
Authors:
A Tanaka; Y Fujimoto
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Journal of chromatography     Volume:  117     ISSN:  0021-9673     ISO Abbreviation:  J. Chromatogr.     Publication Date:  1976 Feb 
Date Detail:
Created Date:  1976-04-19     Completed Date:  1976-04-19     Revised Date:  2000-12-18    
Medline Journal Info:
Nlm Unique ID:  0427043     Medline TA:  J Chromatogr     Country:  NETHERLANDS    
Other Details:
Languages:  eng     Pagination:  149-60     Citation Subset:  IM    
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MeSH Terms
Descriptor/Qualifier:
Chromatography, Gas*
Fruit / analysis*
Methods
Spectrum Analysis / methods
Thiabendazole / analogs & derivatives*,  analysis
Chemical
Reg. No./Substance:
148-79-8/Thiabendazole

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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