Document Detail


Gallium tribromide catalyzed coupling reaction of alkenyl ethers with ketene silyl acetals.
MedLine Citation:
PMID:  22865567     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
A 'Ga'llant couple: The α-alkenylation of esters was accomplished by GaBr(3) -catalyzed coupling between alkenyl ethers and ketene silyl acetals. In this reaction system, various alkenyl ethers, including those with vinyl and substituted alkenyl groups, were applicable, and the scope of applicable ketene silyl acetals was sufficiently broad. The mechanism is also discussed.
Authors:
Yoshihiro Nishimoto; Hiroki Ueda; Makoto Yasuda; Akio Baba
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Publication Detail:
Type:  Journal Article     Date:  2012-07-02
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  51     ISSN:  1521-3773     ISO Abbreviation:  Angew. Chem. Int. Ed. Engl.     Publication Date:  2012 Aug 
Date Detail:
Created Date:  2012-08-06     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  Germany    
Other Details:
Languages:  eng     Pagination:  8073-6     Citation Subset:  IM    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1, Yamada-oka, Suita (Japan).
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