| Fullerenes as Neutral Carbon-Based Lewis Acids. | |
| | |
MedLine Citation:
|
PMID: 22246668 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
|
Lewis adducts between N-heterocyclic carbenes and fullerenes have been isolated and their structures confirmed by X-ray crystallography. This work shows that simple fullerenes such as C(60) or C(70) can act as Lewis acids. This result not only opens new perspectives in fullerene chemistry but might also have strong implications in emerging fields such as the metal-free activation of small molecules. |
| | |
Authors:
|
Javier Iglesias-Sigüenza; Manuel Alcarazo |
Related Documents
:
|
18284238 - Facile synthesis for ordered mesoporous gamma-aluminas with high thermal stability. 18844418 - An efficient approach to chiral c8/c9-piperazino-substituted 1,4-benzodiazepin-2-ones a... 15255688 - Tin(iv) chloride-chiral pyrogallol derivatives as new lewis acid-assisted chiral brøns... 16749768 - Molecular rearrangements of (-)-modhephene and (-)-isocomene to a (-)-triquinane. 20303608 - Development of stress resistance in staphylococcus aureus after exposure to sublethal e... 19739658 - Investigations on the effect of amino acids on acrylamide, pyrazines, and michael addit... |
Publication Detail:
|
Type: JOURNAL ARTICLE Date: 2012-1-13 |
Journal Detail:
|
Title: Angewandte Chemie (International ed. in English) Volume: - ISSN: 1521-3773 ISO Abbreviation: - Publication Date: 2012 Jan |
Date Detail:
|
Created Date: 2012-1-16 Completed Date: - Revised Date: - |
Medline Journal Info:
|
Nlm Unique ID: 0370543 Medline TA: Angew Chem Int Ed Engl Country: - |
Other Details:
|
Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
|
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
|
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany). |
Export Citation:
|
APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
|
|
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
Previous Document: Does the amplatzer septal occluder device alter ventricular contraction pattern? A ventricular motio...
Next Document: A kinetic model for vessel-encoded dynamic angiography with arterial spin labeling.