Document Detail


Fullerenes as Neutral Carbon-Based Lewis Acids.
MedLine Citation:
PMID:  22246668     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Lewis adducts between N-heterocyclic carbenes and fullerenes have been isolated and their structures confirmed by X-ray crystallography. This work shows that simple fullerenes such as C(60) or C(70) can act as Lewis acids. This result not only opens new perspectives in fullerene chemistry but might also have strong implications in emerging fields such as the metal-free activation of small molecules.
Authors:
Javier Iglesias-Sigüenza; Manuel Alcarazo
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-1-13
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  -     ISSN:  1521-3773     ISO Abbreviation:  -     Publication Date:  2012 Jan 
Date Detail:
Created Date:  2012-1-16     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany).
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