Document Detail


From monomers to solids: controlled hydrolysis to form novel, heteroleptic hydroxide-containing complexes.
MedLine Citation:
PMID:  17083255     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
Four novel alkaline earth metal tetranuclear aryloxide/pyrazolate hydroxides of the general formula M4(ligand)6(OH)2(donor)n have been prepared by either adding stoichiometric quantities of water to preformed alkaline earth metal aryloxides or in a direct metalation regime combining metal, ligand (alcohol, pyrazole), and donor with stoichiometric amounts of water. The compounds are considered as potential intermediates in the sol-gel process. A nonhydrolyzable magnesium aryloxide has also been obtained using the same reaction scheme. Unexpectedly, a dimeric strontium complex with further association of a second dimer via hydrogen bonding from the solvent of crystallization, ethylenediamine, has been isolated by the treatment of strontium metal with a mixture of alcohol and water. All compounds were characterized using X-ray crystallography, 1H and 13C NMR, and IR spectroscopy.
Authors:
Weijie Teng; Marites Guino-O; Julia Hitzbleck; Ulrich Englich; Karin Ruhlandt-Senge
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Inorganic chemistry     Volume:  45     ISSN:  0020-1669     ISO Abbreviation:  Inorg Chem     Publication Date:  2006 Nov 
Date Detail:
Created Date:  2006-11-06     Completed Date:  2007-05-31     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0366543     Medline TA:  Inorg Chem     Country:  United States    
Other Details:
Languages:  eng     Pagination:  9531-9     Citation Subset:  -    
Affiliation:
Department of Chemistry and the W. M. Keck Center for Molecular Electronics, Room 1-014, Center for Science and Technology, Syracuse University, Syracuse, New York 13244-4100, USA.
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