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Formation of Fe2O3 Microboxes with Hierarchical Shell Structures from Metal-organic Frameworks and Their Lithium Storage Properties.
MedLine Citation:
PMID:  23057775     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Fe2O3 microboxes with hierarchically structured shells have been synthesized by simply annealing Prussian blue (PB) microcubes. By utilizing simultaneous oxidative decomposition of PB microcubes and crystal growth of iron oxide shells, we have demonstrated a scalable synthesis of anisotropic hollow structures with various shell architectures. When evaluated as an anode material for lithium-ion batteries, the Fe2O3 microboxes with well-defined hollow structure and hierarchical shell manifest high specific capacity (~ 950 mA h g-1 at 200 mA g-1) and excellent cycling performance.
Authors:
Lei Zhang; Hao Bin Wu; Madhavi Srinivasan; Huey Hoon Hng; Xiong Wen David Lou
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-11
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  -     ISSN:  1520-5126     ISO Abbreviation:  J. Am. Chem. Soc.     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-12     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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