Document Detail


Formal C-H amination of cyclopropenes.
MedLine Citation:
PMID:  23034696     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
A novel C(sp(3))-H amination of trimethylsilyl-substituted cyclopropenes is described. This C-H amination proceeds via a tandem regioselective ene reaction between cyclopropenes and azodicarboxylate to generate a hydrazodicarboxylate intermediate followed by its site-selective allylic transposition.
Authors:
Chunrui Sun; Jingwei Li; Daesung Lee; Genping Huang; Yuanzhi Xia
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-4
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-4     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry, University of Illinois at Chicago, Chicago, Illinois 60607, USA. dsunglee@uic.edu.
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