Document Detail


Folate-receptor-mediated delivery of InP quantum dots for bioimaging using confocal and two-photon microscopy.
MedLine Citation:
PMID:  16089466     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
A novel method for the synthesis of highly monodispersed hydrophillic InP-ZnS nanocrystals and their use as luminescence probes for live cell imaging is reported. Hydrophobic InP-ZnS nanocrystals are prepared by a new method that yields high-quality, luminescent core-shell nanocrystals within 6-8 h of total reaction time. Then by carefully manipulating the surface of these passivated nanocrystals, aqueous dispersions of folate-conjugated nanocrystals (folate-QDs) with high photostability are prepared. By use of confocal microscopy, we demonstrate the receptor-mediated delivery of folic acid conjugated quantum dots into folate-receptor-positive cell lines such as KB cells. These folate-QDs tend to accumulate in multi-vescicular bodies of KB cells after 6 h of incubation. Receptor-mediated delivery was confirmed by comparison with the uptake of these particles in folate-receptor-negative cell lines such as A549. Efficient two-photon excitation of these particles and two-photon imaging using these particles are also demonstrated. The use of these InP-ZnS nanoparticles and their efficient two-photon excitation can be potentially useful for deep tissue imaging for future in vivo studies.
Authors:
Dhruba J Bharali; Derrick W Lucey; Harishankar Jayakumar; Haridas E Pudavar; Paras N Prasad
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't; Research Support, U.S. Gov't, Non-P.H.S.    
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  127     ISSN:  0002-7863     ISO Abbreviation:  J. Am. Chem. Soc.     Publication Date:  2005 Aug 
Date Detail:
Created Date:  2005-08-10     Completed Date:  2005-11-21     Revised Date:  2006-11-15    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  United States    
Other Details:
Languages:  eng     Pagination:  11364-71     Citation Subset:  IM    
Affiliation:
Institute for Laser, Photonics and Biophotonics, and Department of Chemistry, The University of Buffalo, Buffalo, New York 14260-3000, USA.
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MeSH Terms
Descriptor/Qualifier:
Biological Transport
Carrier Proteins / metabolism*
Cells, Cultured
Fluorescent Dyes / chemical synthesis,  chemistry*,  metabolism*
Humans
Luminescent Agents / chemical synthesis,  chemistry*,  metabolism*
Microscopy / methods
Microscopy, Confocal*
Microscopy, Fluorescence*
Photons
Quantum Dots*
Receptors, Cell Surface / metabolism*
Chemical
Reg. No./Substance:
0/Carrier Proteins; 0/Fluorescent Dyes; 0/Luminescent Agents; 0/Receptors, Cell Surface; 0/folate-binding protein

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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