Document Detail


Fluorescence enhancement of yttrium(III)-rutin by nucleic acids in the presence of cetyltrimethylammonium bromide.
MedLine Citation:
PMID:  16644263     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
It is found that nucleic acids can enhance the fluorescence intensity of yttrium(III) (Y(3+))-rutin in presence of cetyltrimethylammonium bromide (CTMAB) system. In hexamethylenetetramine (HMTA)-HCl buffer, the maximum enhanced fluorescence is produced, with maximum excitation and emission wavelengths at 452 and 520 nm, respectively. Based on this, a new fluorimetric method of determination of nucleic acids is proposed. Under optimum conditions, the enhanced fluorescence intensity is proportion to the concentration of nucleic acids in the range of 1.0 x 10(-7) to 1.0 x 10(-5)g/ml for fish sperm DNA (fsDNA), 1.0 x 10(-7) to 4.6 x 10(-6)g/ml for yeast RNA (yRNA), their detection limits (S/N=3) are 7.5 x 10(-8), 8.0 x 10(-8)g/ml, respectively. The interaction mechanism is also studied.
Authors:
Xia Wu; Changying Guo; Fei Wang; Jinghe Yang; Dehuan Ran; Jinhua Zheng; Jinbo Wu
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't     Date:  2006-04-27
Journal Detail:
Title:  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy     Volume:  65     ISSN:  1386-1425     ISO Abbreviation:  Spectrochim Acta A Mol Biomol Spectrosc     Publication Date:  2006 Nov 
Date Detail:
Created Date:  2006-10-10     Completed Date:  2007-02-27     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9602533     Medline TA:  Spectrochim Acta A Mol Biomol Spectrosc     Country:  England    
Other Details:
Languages:  eng     Pagination:  543-8     Citation Subset:  IM    
Affiliation:
Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, PR China.
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MeSH Terms
Descriptor/Qualifier:
Animals
Cetrimonium Compounds / chemistry*
DNA / analysis*
Fishes / genetics
Fluorescence
Male
RNA / analysis*
RNA, Fungal / analysis
Rutin / chemistry*
Spectrometry, Fluorescence / methods*
Spermatozoa / chemistry
Yeasts / genetics
Yttrium / chemistry*
Chemical
Reg. No./Substance:
0/Cetrimonium Compounds; 0/RNA, Fungal; 153-18-4/Rutin; 63231-63-0/RNA; 6899-10-1/cetrimonium; 7440-65-5/Yttrium; 9007-49-2/DNA

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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