Document Detail


Fatty acid allene oxides. II. Formation of two macrolactones from 12,13(S)-epoxy-9(Z),11-octadecadienoic acid.
MedLine Citation:
PMID:  3365827     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
An unstable fatty acid allene oxide, 12,13(S)-epoxy-9(Z),11-octadecadienoic acid, was recently identified as the product formed from 13(S)-hydroperoxy-9(Z), 11(E)-octadecadienoic acid in the presence of corn (Zea mays L.) hydroperoxide dehydrase (M. Hamberg (1987) Biochim. Biophys. Acta 920, 76-84). The present paper is concerned with the spontaneous decomposition of 12,13(S)-epoxy-9(Z),11-octadecadienoic acid in acetonitrile solution. Two major products were isolated and characterized, i.e. macrolactones 12-keto-9(Z)-octadecen-11-olide and 12-keto-9(Z)-octadecen-13-olide.
Authors:
M Hamberg
Related Documents :
17112527 - Enzymes of type ii fatty acid synthesis and apicoplast differentiation and division in ...
13921277 - The structure of high molecular weight ribonucleic acid in solution. a smallangle x-ray...
15930577 - Studies into using manure in a biorefinery concept.
7406867 - Retention of the 4-pro-r hydrogen atom of mevalonate at c-2,2' of bacterioruberin in ha...
11842327 - Natural products inhibiting candida albicans secreted aspartic proteases from tovomita ...
7453847 - Potential anticancer agents. xx. 2. quantitative structure--activity relationships (qsa...
Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Chemistry and physics of lipids     Volume:  46     ISSN:  0009-3084     ISO Abbreviation:  Chem. Phys. Lipids     Publication Date:  1988 Apr 
Date Detail:
Created Date:  1988-06-22     Completed Date:  1988-06-22     Revised Date:  2006-11-15    
Medline Journal Info:
Nlm Unique ID:  0067206     Medline TA:  Chem Phys Lipids     Country:  NETHERLANDS    
Other Details:
Languages:  eng     Pagination:  235-43     Citation Subset:  IM    
Affiliation:
Department of Physiological Chemistry, Karolinska Institutet, Stockholm, Sweden.
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:
Fatty Acids, Unsaturated*
Linoleic Acids*
Oleic Acids*
Chemical
Reg. No./Substance:
0/Fatty Acids, Unsaturated; 0/Linoleic Acids; 0/Oleic Acids; 114416-54-5/12-keto-9(2)-octadecen-11-olide; 114416-55-6/12-keto-9(2)-octadecen-13-olide; 114488-95-8/12,13-epoxy-9(2),11-octadecadienoic acid; 26764-25-0/octadecadienoic acid

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


Previous Document:  Studies on the base pair binding specificity of CC-1065 to oligomer duplexes.
Next Document:  Inhibitors of sterol synthesis. Concerning the structure of 15 beta-methyl-5 alpha,14 beta-cholest-7...