Document Detail


Facile formation of N-acyl-oxazolidinone derivatives using acid fluorides.
MedLine Citation:
PMID:  20707372     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
A mild method is presented for the formation of N-acylated oxazolidinones that employs acid fluorides and mild bases, such as (i)Pr(2)NEt and NEt(3). Optimized reaction conditions for two types of substrates have been developed utilizing either the oxazolidinone itself or the corresponding in situ generated O-silyloxazolidinones resulting in the formation of the desired N-acylated products in high yields of up to 98%.
Authors:
Corinna S Schindler; Patrik M Forster; Erick M Carreira
Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Organic letters     Volume:  12     ISSN:  1523-7052     ISO Abbreviation:  Org. Lett.     Publication Date:  2010 Sep 
Date Detail:
Created Date:  2010-09-10     Completed Date:  2010-12-21     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  United States    
Other Details:
Languages:  eng     Pagination:  4102-5     Citation Subset:  IM    
Affiliation:
Laboratorium für Organische Chemie, ETH Zürich, Wolfgang-Pauli-Strasse 10, 8093 Zürich, Switzerland.
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MeSH Terms
Descriptor/Qualifier:
Acids / chemistry*
Acylation
Fluorides / chemistry*
Molecular Structure
Oxazolidinones / chemical synthesis*
Chemical
Reg. No./Substance:
0/Acids; 0/Fluorides; 0/Oxazolidinones

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