Document Detail


Experimental study on moving neutralization reaction boundary created with the strong reactive electrolytes of HCl and NaOH in agarose gel.
MedLine Citation:
PMID:  11043794     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
In this paper, a moving neutralization reaction boundary (MNRB) is created with the strong reactive electrolytes of HCl and NaOH in agarose gel. The motions of the MNRB are investigated and compared with the predictions with the theory of the moving chemical reaction boundary (MCRB). The results show that, under appreciate experimental conditions, the experiments on the MNRB are exactly in coincidence with the predictions with the MCRB theory. Thus, the results excellently demonstrate that the MCRB theory is valid for the MNRB formed with the strong reactive electrolytes of HCl and NaOH. Additionally, it is, as discussed in this paper, imperative to develop a method to obtain ionic mobility at different temperatures and ionic strengths, in order to investigate the movements of the MCRB more efficiently.
Authors:
C X Cao; S L Zhou; H You-Zhao; X Y Zheng; W K Chen; Y A Qian
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Journal of chromatography. A     Volume:  891     ISSN:  0021-9673     ISO Abbreviation:  J Chromatogr A     Publication Date:  2000 Sep 
Date Detail:
Created Date:  2001-02-06     Completed Date:  2001-02-08     Revised Date:  2009-01-15    
Medline Journal Info:
Nlm Unique ID:  9318488     Medline TA:  J Chromatogr A     Country:  NETHERLANDS    
Other Details:
Languages:  eng     Pagination:  337-47     Citation Subset:  IM    
Affiliation:
Department of Chemistry, University of Science and Technology of China, Hefei. cxcao@mail.ustc.edu.cn
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MeSH Terms
Descriptor/Qualifier:
Electrolytes / chemistry*
Hydrochloric Acid / chemistry*
Osmolar Concentration
Reproducibility of Results
Sepharose / chemistry*
Sodium Hydroxide / chemistry*
Temperature
Chemical
Reg. No./Substance:
0/Electrolytes; 1310-73-2/Sodium Hydroxide; 7647-01-0/Hydrochloric Acid; 9012-36-6/Sepharose

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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