Document Detail

Experimental investigation and modeling of the kinetics of CCl(4) pyrolysis behind reflected shock waves using high-repetition-rate time-of-flight mass spectrometry.
MedLine Citation:
PMID:  23338791     Owner:  NLM     Status:  Publisher    
The pyrolysis kinetics of CCl(4) behind reflected shock waves was studied with high-repetition-rate time-of-flight mass spectrometry. For modeling, quantum mechanical calculations were performed to evaluate the dissociation energies of CCl bonds for the different CCl(x) (x = 1 to 4) radicals. Good agreement with the JANAF thermochemical table was found. With the reaction mechanism developed for CCl(4) decomposition satisfactory agreement with experimental results was obtained. The investigations show the importance of C(2)Cl(2) formation for understanding the processes of carbon cluster growth leading to carbonaceous particle formation.
M Aghsaee; A Drakon; A Eremin; S H Dürrstein; H Böhm; H Somnitz; M Fikri; C Schulz
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-22
Journal Detail:
Title:  Physical chemistry chemical physics : PCCP     Volume:  -     ISSN:  1463-9084     ISO Abbreviation:  Phys Chem Chem Phys     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-22     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100888160     Medline TA:  Phys Chem Chem Phys     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
IVG, Institute for Combustion of Gasdynamics, University of Duisburg-Essen, Duisburg, Germany.
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