| Experimental investigation and modeling of the kinetics of CCl(4) pyrolysis behind reflected shock waves using high-repetition-rate time-of-flight mass spectrometry. | |
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MedLine Citation:
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PMID: 23338791 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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The pyrolysis kinetics of CCl(4) behind reflected shock waves was studied with high-repetition-rate time-of-flight mass spectrometry. For modeling, quantum mechanical calculations were performed to evaluate the dissociation energies of CCl bonds for the different CCl(x) (x = 1 to 4) radicals. Good agreement with the JANAF thermochemical table was found. With the reaction mechanism developed for CCl(4) decomposition satisfactory agreement with experimental results was obtained. The investigations show the importance of C(2)Cl(2) formation for understanding the processes of carbon cluster growth leading to carbonaceous particle formation. |
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Authors:
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M Aghsaee; A Drakon; A Eremin; S H Dürrstein; H Böhm; H Somnitz; M Fikri; C Schulz |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2013-1-22 |
Journal Detail:
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Title: Physical chemistry chemical physics : PCCP Volume: - ISSN: 1463-9084 ISO Abbreviation: Phys Chem Chem Phys Publication Date: 2013 Jan |
Date Detail:
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Created Date: 2013-1-22 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 100888160 Medline TA: Phys Chem Chem Phys Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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IVG, Institute for Combustion of Gasdynamics, University of Duisburg-Essen, Duisburg, Germany. mustapha.fikri@uni-due.de. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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