| Expanding Family of π-Conjugated Trinuclear Dithiolenes: The Cases of Group 8 (Ru(II)) and 10 (Ni(II) and Pt(II)) Metals. | |
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MedLine Citation:
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PMID: 21736302 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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New π-conjugated trinuclear dithiolenes with group 8 (6, Ru(II)) and 10 (7 and 8, Ni(II) and Pt(II)) metals were synthesized. Compounds 6 and 7 exhibited intense electronic communication through the phenylene bridge among the three dithiolene moieties during oxidation of the metalladithiolene rings, which has not been confirmed in the analogous family of group 9 metals, 1-5. Compound 8 exhibited an intense absorption band across the visible and near-IR regions, which was assigned as a charge transfer to the diimine and was red-shifted and broadened compared to the corresponding band of the mononuclear complex. |
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Authors:
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Tetsuya Kambe; Satoru Tsukada; Ryota Sakamoto; Hiroshi Nishihara |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2011-7-7 |
Journal Detail:
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Title: Inorganic chemistry Volume: - ISSN: 1520-510X ISO Abbreviation: - Publication Date: 2011 Jul |
Date Detail:
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Created Date: 2011-7-8 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0366543 Medline TA: Inorg Chem Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Department of Chemistry, Graduate School of Science, The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033 Japan. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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