Document Detail

Exchange-coupled oxygen- and sulfur-bridged cyclopentadienyl-manganese(ii) cages.
MedLine Citation:
PMID:  23143670     Owner:  NLM     Status:  Publisher    
The trimetallic complex [{CpMn(μ-OSiPh(3))(2)}(2)Mn] () and the heterocubane [CpMn(μ(3)-SSiPh(3))](4) () are formed by deprotonation of Ph(3)SiQH (Q = O, S) by manganocene, or by transmetallation of manganocene by Ph(3)SiQLi. The Mn(ii) centres in and are antiferromagnetically coupled, with J = -4.4 and -3.0 cm(-1) in and , respectively (-2J formalism).
Charlene A Smith; Floriana Tuna; Michael Bodensteiner; Madeleine Helliwell; David Collison; Richard A Layfield
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-12
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  -     ISSN:  1477-9234     ISO Abbreviation:  Dalton Trans     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-12     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
School of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
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