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Ex situ NMR in highly homogeneous fields: 1H spectroscopy.
MedLine Citation:
PMID:  17218492     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
Portable single-sided nuclear magnetic resonance (NMR) magnets used for nondestructive studies of large samples are believed to generate inherently inhomogeneous magnetic fields. We demonstrated experimentally that the field of an open magnet can be shimmed to high homogeneity in a large volume external to the sensor. This technique allowed us to measure localized high-resolution proton spectra outside a portable open magnet with a spectral resolution of 0.25 part per million. The generation of these experimental conditions also simplifies the implementation of such powerful methodologies as multidimensional NMR spectroscopy and imaging.
Authors:
Juan Perlo; Federico Casanova; Bernhard Blümich
Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't     Date:  2007-01-11
Journal Detail:
Title:  Science (New York, N.Y.)     Volume:  315     ISSN:  1095-9203     ISO Abbreviation:  Science     Publication Date:  2007 Feb 
Date Detail:
Created Date:  2007-02-26     Completed Date:  2007-03-07     Revised Date:  2007-03-19    
Medline Journal Info:
Nlm Unique ID:  0404511     Medline TA:  Science     Country:  United States    
Other Details:
Languages:  eng     Pagination:  1110-2     Citation Subset:  -    
Affiliation:
Institut für Technische Chemie und Makromolekulare Chemie, Rheinisch-Westfälische Technische Hochschule-Aachen, D-52056, Germany.
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