Document Detail


Evaluation of aquatic toxicities of chromium and chromium-containing effluents in reference to chromium electroplating industries.
MedLine Citation:
PMID:  16418891     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
This study evaluated aquatic toxicities of chromium and chromium-containing laboratory samples representative of effluents from chromium electroplating industries, and compared the aquatic environmental risks of hexavalent and trivalent chromium electroplating operations. Trivalent chromium electroplating has emerged as an acceptable alternative to hazardous hexavalent chromium electroplating. This process substitution has reduced the human health impact in the workplace and minimized the production of hazardous sludge regulated under the Resource Conservation and Recovery Act (RCRA). The thrust behind this research was to investigate whether trivalent chromium electroplating operations have lower adverse impacts on standardized toxicity test organisms. Ceriodaphnia dubia and Pimephales promelas were used to investigate toxicities of trivalent chromium (Cr (III)), hexavalent chromium (Cr (VI)), and industrial effluents. In agreement with previous studies, Cr (III) was found to be less toxic than Cr (VI). Despite having several organic and inorganic constituents in the effluents obtained from trivalent chromium plating baths, they exhibited less adverse effects to C. dubia than effluents obtained from hexavalent chromium electroplating baths. Thus, transition from hexavalent to trivalent chromium electroplating processes may be justified. However, because of the presence of organic constituents such as formate, oxalate, and triethylene glycol in effluents, trivalent chromium electroplating operations may face additional regulatory requirements for removal of total organic carbon.
Authors:
A Baral; R Engelken; W Stephens; J Farris; R Hannigan
Publication Detail:
Type:  Journal Article     Date:  2006-01-13
Journal Detail:
Title:  Archives of environmental contamination and toxicology     Volume:  50     ISSN:  0090-4341     ISO Abbreviation:  Arch. Environ. Contam. Toxicol.     Publication Date:  2006 May 
Date Detail:
Created Date:  2006-04-05     Completed Date:  2006-05-05     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0357245     Medline TA:  Arch Environ Contam Toxicol     Country:  United States    
Other Details:
Languages:  eng     Pagination:  496-502     Citation Subset:  IM    
Affiliation:
A. Baral, Irving, Texas 75016, USA.
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MeSH Terms
Descriptor/Qualifier:
Animals
Chromium / toxicity*
Cyprinidae / growth & development*
Daphnia / drug effects*
Electroplating
Metallurgy
Toxicity Tests*
Water Pollutants, Chemical / toxicity*
Chemical
Reg. No./Substance:
0/Water Pollutants, Chemical; 7440-47-3/Chromium

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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