Document Detail


Equimolar CO(2) Capture by N-Substituted Amino Acid Salts and Subsequent Conversion.
MedLine Citation:
PMID:  23042720     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Steric bulk controls CO(2) absorption: N-substituted amino acid salts in poly(ethylene glycol) reversibly absorb CO(2) in nearly 1:1 stoichiometry. Carbamic acid is thought to be the absorbed form of CO(2) ; this was supported by NMR and in situ IR spectroscopy, and DFT calculations. The captured CO(2) could be converted directly into oxazolidinones and thus CO(2) desorption could be sidestepped.
Authors:
An-Hua Liu; Ran Ma; Chan Song; Zhen-Zhen Yang; Ao Yu; Yu Cai; Liang-Nian He; Ya-Nan Zhao; Bing Yu; Qing-Wen Song
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-8
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  -     ISSN:  1521-3773     ISO Abbreviation:  Angew. Chem. Int. Ed. Engl.     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-8     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071 (P.R. China).
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