| Equimolar CO(2) Capture by N-Substituted Amino Acid Salts and Subsequent Conversion. | |
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MedLine Citation:
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PMID: 23042720 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Steric bulk controls CO(2) absorption: N-substituted amino acid salts in poly(ethylene glycol) reversibly absorb CO(2) in nearly 1:1 stoichiometry. Carbamic acid is thought to be the absorbed form of CO(2) ; this was supported by NMR and in situ IR spectroscopy, and DFT calculations. The captured CO(2) could be converted directly into oxazolidinones and thus CO(2) desorption could be sidestepped. |
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Authors:
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An-Hua Liu; Ran Ma; Chan Song; Zhen-Zhen Yang; Ao Yu; Yu Cai; Liang-Nian He; Ya-Nan Zhao; Bing Yu; Qing-Wen Song |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-10-8 |
Journal Detail:
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Title: Angewandte Chemie (International ed. in English) Volume: - ISSN: 1521-3773 ISO Abbreviation: Angew. Chem. Int. Ed. Engl. Publication Date: 2012 Oct |
Date Detail:
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Created Date: 2012-10-8 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0370543 Medline TA: Angew Chem Int Ed Engl Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071 (P.R. China). |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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