| Enzymatic resolution of (+/-)-gamma-cyclohomogeraniol and conversion of its (S)-isomer to (S)-gamma-coronal, the ambergris odorant. | |
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MedLine Citation:
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PMID: 10400325 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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Enzymatic acetylation of (+/-)-gamma-cyclohomogeraniol[2-(2',2'-dimethyl-6'-methylenecyc lohexyl)ethanol] with vinyl acetate in the presence of lipase AK yielded the acetate of its (R)-isomer, leaving its (S)-isomer intact. The (S)-isomer was chemically converted to (S)-gamma-coronal[2-methylene-4-(2',2'-dimethyl-6'-methylenecyclohexy l)butanal], the ambergris odorant. |
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Authors:
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S Horiuchi; H Takikawa; K Mori |
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Publication Detail:
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Type: Journal Article; Research Support, Non-U.S. Gov't |
Journal Detail:
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Title: Bioorganic & medicinal chemistry Volume: 7 ISSN: 0968-0896 ISO Abbreviation: Bioorg. Med. Chem. Publication Date: 1999 May |
Date Detail:
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Created Date: 1999-10-28 Completed Date: 1999-10-28 Revised Date: 2006-11-15 |
Medline Journal Info:
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Nlm Unique ID: 9413298 Medline TA: Bioorg Med Chem Country: ENGLAND |
Other Details:
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Languages: eng Pagination: 723-6 Citation Subset: IM |
Affiliation:
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Department of Chemistry, Faculty of Science, Science University of Tokyo, Japan. |
Export Citation:
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APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
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Alkanes
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chemical synthesis*,
chemistry* Ambergris / chemistry* Cyclohexanes / chemical synthesis*, chemistry* Ethanol / chemical synthesis*, chemistry* Isomerism Models, Chemical Terpenes / chemistry*, metabolism* |
| Chemical | |
Reg. No./Substance:
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0/2-(2',2'-dimethyl-6'-methylenecyclohexyl)ethanol; 0/2-methylene-4-(2',2'-dimethyl-6'-methylenecyclohexyl)ethanol; 0/Alkanes; 0/Ambergris; 0/Cyclohexanes; 0/Terpenes; 624-15-7/geraniol; 64-17-5/Ethanol |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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