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Enzymatic biodiesel synthesis using a byproduct obtained from palm oil refining.
MedLine Citation:
PMID:  21687622     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
An alternative route to produce biodiesel is based on esterification of free fatty acids present in byproducts obtained from vegetable oil refining, such as palm oil fatty acid distillate (PFAD). PFAD is a byproduct of the production of edible palm oil, which contains 96 wt.% of free fatty acids. The purpose of this work was to study biodiesel synthesis via esterification of PFAD with methanol and ethanol, catalyzed by commercial immobilized lipases (Novozym 435, Lipozyme RM-IM, and Lipozyme TL-IM), in a solvent-free system. The effects of reaction parameters such as type of lipase, enzyme amount, type of alcohol, alcohol amount, and enzyme reuse were studied. Fatty acid conversion of 93% was obtained after 2.5 h of esterification reaction between PFAD and ethanol using 1.0 wt.% of Novozym 435 at 60°C.
Authors:
Igor Nascentes Dos Santos Corrêa; Susana Lorena de Souza; Marly Catran; Otávio Luiz Bernardes; Márcio Figueiredo Portilho; Marta Antunes Pereira Langone
Publication Detail:
Type:  Journal Article     Date:  2011-05-26
Journal Detail:
Title:  Enzyme research     Volume:  2011     ISSN:  2090-0414     ISO Abbreviation:  Enzyme Res     Publication Date:  2011  
Date Detail:
Created Date:  2011-06-20     Completed Date:  2011-07-14     Revised Date:  2011-08-01    
Medline Journal Info:
Nlm Unique ID:  101536666     Medline TA:  Enzyme Res     Country:  England    
Other Details:
Languages:  eng     Pagination:  814507     Citation Subset:  -    
Affiliation:
Institute of Chemistry, Rio de Janeiro State University, Rua São Francisco Xavier 524, PHLC/IQ sala 310, Rio de Janeiro, RJ 20550-013, Brazil.
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