Document Detail

Enhancing catalytic selectivity of supported metal nanoparticles with capping ligands.
MedLine Citation:
PMID:  23303365     Owner:  NLM     Status:  Publisher    
Enhancing catalytic selectivity of supported metal nanoparticles with capping ligands is demonstrated using an Au/SiO(2) catalyst in liquid phase aerobic oxidation of benzyl alcohol. Chemisorption of an appropriate amount of polyvinylpyrrolidone on the Au/SiO(2) catalyst greatly enhances the benzaldehyde selectivity from 43% to ∼100% and its yield from 4.9% to 7.2%.
Kai Chen; Haotian Wu; Qing Hua; Sujie Chang; Weixin Huang
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-10
Journal Detail:
Title:  Physical chemistry chemical physics : PCCP     Volume:  -     ISSN:  1463-9084     ISO Abbreviation:  Phys Chem Chem Phys     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-10     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100888160     Medline TA:  Phys Chem Chem Phys     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Chemistry Experimental Teaching Center, University of Science and Technology of China, Hefei 230026, China.
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