Document Detail


Enantioselective conjugate addition of boronic acids to enones catalyzed by O-monoacyltartaric acids.
MedLine Citation:
PMID:  20852820     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
We have found that O-monoacyltartaric acids catalyze asymmetric conjugate addition of boronic acids to enones with good enantioselectivity, and the 3,5-di(tert-butyl)benzoyl group provides the best results among the acyl groups examined.
Authors:
Masaharu Sugiura; Mirai Tokudomi; Makoto Nakajima
Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't     Date:  2010-09-20
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  46     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2010 Nov 
Date Detail:
Created Date:  2010-10-12     Completed Date:  2011-01-21     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  England    
Other Details:
Languages:  eng     Pagination:  7799-800     Citation Subset:  IM    
Affiliation:
Graduate School of Pharmaceutical Sciences, Kumamoto University, 5-1 Oe-honmachi, Kumamoto 862-0973, Japan. msugiura@kumamoto-u.ac.jp
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MeSH Terms
Descriptor/Qualifier:
Alkenes / chemistry*
Boronic Acids / chemistry*
Catalysis
Ketones / chemistry*
Stereoisomerism
Substrate Specificity
Tartrates / chemistry*
Chemical
Reg. No./Substance:
0/Alkenes; 0/Boronic Acids; 0/Ketones; 0/Tartrates; 526-83-0/tartaric acid

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