Document Detail


Enantioselective rhodium-catalyzed addition of arylboronic acids to alkenylheteroarenes.
MedLine Citation:
PMID:  20879736     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
In the presence of a rhodium complex containing a newly developed chiral diene ligand, alkenes activated by a range of π-deficient or π-excessive heteroarenes engage in highly enantioselective conjugate additions with various arylboronic acids.
Authors:
Graham Pattison; Guillaume Piraux; Hon Wai Lam
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  132     ISSN:  1520-5126     ISO Abbreviation:  J. Am. Chem. Soc.     Publication Date:  2010 Oct 
Date Detail:
Created Date:  2010-10-13     Completed Date:  2011-01-21     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  United States    
Other Details:
Languages:  eng     Pagination:  14373-5     Citation Subset:  IM    
Affiliation:
School of Chemistry, University of Edinburgh, Joseph Black Building, The King's Buildings, West Mains Road, Edinburgh, EH9 3JJ, United Kingdom.
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MeSH Terms
Descriptor/Qualifier:
Acids, Heterocyclic / chemistry*
Boronic Acids / chemistry*
Catalysis
Rhodium / chemistry*
Stereoisomerism
Chemical
Reg. No./Substance:
0/Acids, Heterocyclic; 0/Boronic Acids; 7440-16-6/Rhodium

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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