| Enantiodivergent, catalytic asymmetric synthesis of gamma-amino vinyl sulfones. | |
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MedLine Citation:
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PMID: 12816460 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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A set of diversely substituted N-Boc-gamma-amino vinyl sulfones has been prepared by a four-step procedure from readily available, highly enantiopure anti-N-Boc-3-amino-1,2-alkanediols. This new route, which does not depend on the accessibility of alpha-amino acids as starting materials, is noteworthy for its efficiency, for its generality, and for the fact that both enantiomers of a given gamma-amino vinyl sulfone can be obtained with equal ease. |
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Authors:
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Anna Picó; Albert Moyano; Miquel A Pericàs |
Publication Detail:
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Type: Journal Article |
Journal Detail:
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Title: The Journal of organic chemistry Volume: 68 ISSN: 0022-3263 ISO Abbreviation: J. Org. Chem. Publication Date: 2003 Jun |
Date Detail:
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Created Date: 2003-06-20 Completed Date: 2004-02-10 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 2985193R Medline TA: J Org Chem Country: United States |
Other Details:
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Languages: eng Pagination: 5075-83 Citation Subset: - |
Affiliation:
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Unitat de Recerca en Síntesi Asimètrica, Departament de Química Orgànica, Facultat de Química, Universitat de Barcelona, Martí i Franquès 1-11, 08028-Barcelona, Spain. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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