Document Detail


Elucidation of Tetraboric Acid with a New Borate Fundamental Building Block in a Chiral Uranyl Fluoroborate.
MedLine Citation:
PMID:  23088377     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
A new neutral borate species, H(2)B(4)O(7) (also known as tetraboric acid), with a one-dimensional chain structure, is found in the interlayer spacing in Rb(2)[(UO(2))(2)B(8)O(12)F(6)]·H(2)B(4)O(7) (RbUBOF-2) derived from boric acid flux reaction of uranyl(VI) nitrate with RbBF(4). This new form of tetraboric acid possesses a novel borate fundamental building block with the symbol 4Δ:⟨3Δ⟩Δ.
Authors:
Shuao Wang; T Gannon Parker; Daniel J Grant; Juan Diwu; Evgeny V Alekseev; Wulf Depmeier; Laura Gagliardi; Thomas E Albrecht-Schmitt
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-22
Journal Detail:
Title:  Inorganic chemistry     Volume:  -     ISSN:  1520-510X     ISO Abbreviation:  Inorg Chem     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-23     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0366543     Medline TA:  Inorg Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Civil Engineering and Geological Sciences and Department of Chemistry and Biochemistry, 156 Fitzpatrick Hall, University of Notre Dame , Notre Dame, Indiana 46556, United States.
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