Document Detail

Electronic structure and geometries of o-carborane derived cyclic structures [{μ-1,2-(C(2)B(10)H(10))(n)M(n)}Ag(m)](z-), M = {Au, Hg}, n = {3, 4}, m = {0, 1, 2}, z = {n - m, -m}
MedLine Citation:
PMID:  23032998     Owner:  NLM     Status:  Publisher    
To date, crystal structures of the cyclic mercury complexes [μ-1,2-(C(2)B(10)H(10))(n)Hg(n)], with n = {3, 4}, have been found. However, the same structures substituting Hg by Au, which implies a charge z = {-3, -4} for n = {3, 4} respectively, have not been found. In this work, we present geometrical and electronic structure properties of the title structures [μ-1,2-(C(2)B(10)H(10))(n)M(n)](z-), M = {Au, Hg}, n = {3, 4}, z = {n, 0}, and study the stability of structures with one and two added Ag(+) ions.
Gabriel Aullón; Antonio Laguna; Josep M Oliva
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-3
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  -     ISSN:  1477-9234     ISO Abbreviation:  Dalton Trans     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-3     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Departamento de Química Inorgànica and Institut de Química Teòrica i Computacional (IQTCUB), Universitat de Barcelona, Diagonal 647, 08028, Barcelona, Spain.
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