| Electronic and EPR spectra of the species involved in [W(10)O(32)](4-) photocatalysis. A relativistic DFT investigation. | |
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MedLine Citation:
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PMID: 23338044 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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The decatungstate anion [W(10)O(32)](4-) is widely used as a photocatalyst in different transformations, during which it undergoes one-electron reduction to [W(10)O(32)](5-), possibly protonated; the bi-reduced species [W(10)O(32)](6-) is obtained by ensuing disproportionation. Relativistic DFT calculations were used to predict the UV-VIS spectra and EPR parameters of all such species. |
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Authors:
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Davide Ravelli; Daniele Dondi; Maurizio Fagnoni; Angelo Albini; Alessandro Bagno |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2013-1-22 |
Journal Detail:
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Title: Physical chemistry chemical physics : PCCP Volume: - ISSN: 1463-9084 ISO Abbreviation: Phys Chem Chem Phys Publication Date: 2013 Jan |
Date Detail:
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Created Date: 2013-1-22 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 100888160 Medline TA: Phys Chem Chem Phys Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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PhotoGreen Lab, Department of Chemistry, University of Pavia, viale Taramelli 12, 27100 Pavia, Italy. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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