Document Detail


Electron spectroscopy and scanning tunneling microscopy study of quasi-two-dimensional freezing at the liquid/vapor interface of Ga-Bi alloys.
MedLine Citation:
PMID:  15634163     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
We have studied the interfacial characteristics of Ga-rich liquid Ga-Bi alloys at various compositions and temperatures up to 300 degrees C by different electron spectroscopies under ultrahigh vacuum conditions. In particular, the thickness and thickness profiles of Bi-rich wetting and surface freezing films have been measured. It is found that at the surface freezing transition the Bi film thickness jumps from approximately 5 A to macroscopic values of over 100 A. This distinct behavior is discussed in comparison with the results in Ga-Pb. In addition, we report first scanning tunneling microscopy observations of the surface structure of a solidified Ga(0.989)Bi(0.011) alloy after passing a surface freezing transition. The topology at room temperature is characterized by extended, atomically flat Bi terraces covered by nanosized triangular two-dimensional Bi islands.
Authors:
A Issanin; A Turchanin; W Freyland
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  The Journal of chemical physics     Volume:  121     ISSN:  0021-9606     ISO Abbreviation:  J Chem Phys     Publication Date:  2004 Dec 
Date Detail:
Created Date:  2005-01-06     Completed Date:  2006-08-11     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0375360     Medline TA:  J Chem Phys     Country:  United States    
Other Details:
Languages:  eng     Pagination:  12005-9     Citation Subset:  -    
Copyright Information:
(c) 2004 American Institute of Physics
Affiliation:
Institute of Physical Chemistry, University of Karlsruhe (TH), Kaiserstrasse 12, D-76128 Karlsruhe, Germany.
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