| Electron Transfer Reduction of Carboxylic Acids Using SmI(2)-H(2)O-Et(3)N. | |
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MedLine Citation:
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PMID: 22272578 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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The first general method for efficient electron transfer reduction of carboxylic acids has been developed. The protocol using SmI(2)-H(2)O-Et(3)N allows for reduction of a variety of carboxylic acids in excellent yields and provides an attractive alternative to processes mediated by reactive alkali metals, lithium aluminum hydride, and boron hydrides. Of broader significance, the method allows acyl radical equivalents to be generated from carboxylic acids under mild reaction conditions. |
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Authors:
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Michal Szostak; Malcolm Spain; David J Procter |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-1-24 |
Journal Detail:
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Title: Organic letters Volume: - ISSN: 1523-7052 ISO Abbreviation: - Publication Date: 2012 Jan |
Date Detail:
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Created Date: 2012-1-25 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 100890393 Medline TA: Org Lett Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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School of Chemistry, University of Manchester , Oxford Road, Manchester, M13 9PL, United Kingdom. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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