Document Detail


Electrochemical properties of polycyclic compounds studied by the polarographic method in anhydrous systems. III. Polarographic reduction potentials of carcinogenic nitrogen compounds in dimethylsulfoxide.
MedLine Citation:
PMID:  1004658     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
The polarographic reduction of a series carcinogenic and noncarcinogenic polycyclic nitrogen compounds in anhydrous dimethylsulfoxide containing tetrabuthylammonium perchlorate as supporting electrolyte has been studied. The obtained results were compared with the number or with the position of nitrogen atoms in the molecules and with their carcinogenic activity. The values of half-waves potentials generally confirmed the mechanism proposed for the reduction of aromatic polycyclic carcinogenic hydrocarbons based on the polarographic experiments in dimethylsulfoxide. Agreement of the obtained results with the data reported by polarographic study in anhydrous dimethylformamide indicates, that the polarographic behavior of polycyclic nitrogen compounds in dimethylsulfoxide is very similar.
Authors:
V Podaný; A Vachálková; L Bahna
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Neoplasma     Volume:  23     ISSN:  0028-2685     ISO Abbreviation:  Neoplasma     Publication Date:  1976  
Date Detail:
Created Date:  1977-02-26     Completed Date:  1977-02-26     Revised Date:  2000-12-18    
Medline Journal Info:
Nlm Unique ID:  0377266     Medline TA:  Neoplasma     Country:  CZECHOSLOVAKIA    
Other Details:
Languages:  eng     Pagination:  617-22     Citation Subset:  IM    
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MeSH Terms
Descriptor/Qualifier:
Acridines*
Anthracenes*
Carbazoles*
Carcinogens*
Dimethyl Sulfoxide
Dimethylformamide
Electrochemistry
Polarography
Pyrenes*
Chemical
Reg. No./Substance:
0/Acridines; 0/Anthracenes; 0/Carbazoles; 0/Carcinogens; 0/Pyrenes; 67-68-5/Dimethyl Sulfoxide; 68-12-2/Dimethylformamide

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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