| Electrochemical control of the regioselectivity in the exohedral functionalization of C(60): the role of aromaticity. | |
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MedLine Citation:
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PMID: 23282733 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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In this work we show that the regioselectivity of the Diels-Alder, 1,3-dipolar, and carbene cycloadditions to C(60) changes from the usual [6,6] addition in neutral species to the [5,6] attack when the number of electrons added to the fullerenic cage increases. Changes in the aromaticity of the five- and six-membered rings of C(60) during the reduction process provide a rationale to understand this regioselectivity change. |
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Authors:
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Marc Garcia-Borràs; Sílvia Osuna; Marcel Swart; Josep M Luis; Miquel Solà |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2013-1-3 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: - ISSN: 1364-548X ISO Abbreviation: Chem. Commun. (Camb.) Publication Date: 2013 Jan |
Date Detail:
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Created Date: 2013-1-3 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Institut de Química Computacional and Departament de Química, Universitat de Girona, Campus Montilivi, 17071 Girona, Catalonia, Spain. miquel.sola@udg.edu. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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