Document Detail


Electrochemical control of the regioselectivity in the exohedral functionalization of C(60): the role of aromaticity.
MedLine Citation:
PMID:  23282733     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
In this work we show that the regioselectivity of the Diels-Alder, 1,3-dipolar, and carbene cycloadditions to C(60) changes from the usual [6,6] addition in neutral species to the [5,6] attack when the number of electrons added to the fullerenic cage increases. Changes in the aromaticity of the five- and six-membered rings of C(60) during the reduction process provide a rationale to understand this regioselectivity change.
Authors:
Marc Garcia-Borràs; Sílvia Osuna; Marcel Swart; Josep M Luis; Miquel Solà
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-3
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-3     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Institut de Química Computacional and Departament de Química, Universitat de Girona, Campus Montilivi, 17071 Girona, Catalonia, Spain. miquel.sola@udg.edu.
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