| Electrochemical carboxylation of alpha-chloroethylbenzene in ionic liquids compressed with carbon dioxide. | |
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MedLine Citation:
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PMID: 20145864 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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Electrochemical carboxylation is conducted in ionic liquids compressed with carbon dioxide. It is found that the current efficiency increases with temperature and pressure. The diffusion coefficient of the substrate, which is obtained from the electrochemical measurements, also remarkably increases with temperature and pressure. The increase of the current efficiency is mainly explained by improvement in the mass transfer, and the promotion of the electrochemical carboxylation in the ionic liquid is achieved by pressurizing the carbon dioxide moderately. |
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Authors:
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Yusuke Hiejima; Masahiro Hayashi; Akihiro Uda; Seiko Oya; Hiroyuki Kondo; Hisanori Senboku; Kenji Takahashi |
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Publication Detail:
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Type: Journal Article Date: 2010-01-20 |
Journal Detail:
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Title: Physical chemistry chemical physics : PCCP Volume: 12 ISSN: 1463-9084 ISO Abbreviation: Phys Chem Chem Phys Publication Date: 2010 Feb |
Date Detail:
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Created Date: 2010-02-10 Completed Date: 2010-04-28 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 100888160 Medline TA: Phys Chem Chem Phys Country: England |
Other Details:
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Languages: eng Pagination: 1953-7 Citation Subset: - |
Affiliation:
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Graduate School of Natural Science and Technology, Kanazawa University, Kanazawa 920-1192, Japan. hiejima@t.kanazawa-u.ac.jp |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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