| Electrocatalysis of chloroacetic acids (mono-, di- and tri-) at a C60-[dimethyl-(beta-cyclodextrin)]2 and nafion chemically modified electrode. | |
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MedLine Citation:
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PMID: 18968196 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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The C(60)-[dimethyl-(beta-cyclodextrin)](2) and nafion chemically modified electrode (CME) exhibits one electroreduction peak and two electro-oxidation peaks in a mixed solvent of water and acetonitrile (3:2, v/v) containing tetra-butylammonium perchlorate. The reduction of chloroacetic acids (mono-, di- and tri-) can be electrocatalyzed at this electrode, indicating that C(60)-[dimethyl-(beta-cyclodextrin)](2) is capable of mediating the electron transfer to chloroacetic acids. Values of the apparent catalytic rate constant, k, were determined by using the rotating-disk electrode (RDE). |
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Authors:
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M Wei; M Li; N Li; Z Gu; X Zhou |
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Publication Detail:
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Type: Journal Article |
Journal Detail:
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Title: Talanta Volume: 53 ISSN: 1873-3573 ISO Abbreviation: Talanta Publication Date: 2001 Jan |
Date Detail:
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Created Date: 2008-10-30 Completed Date: 2009-12-15 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 2984816R Medline TA: Talanta Country: England |
Other Details:
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Languages: eng Pagination: 1045-52 Citation Subset: - |
Affiliation:
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Department of Chemistry, Institute of Physical Chemistry, Peking University, Beijing, People's Republic of China. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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