Document Detail

Electrocatalysis of chloroacetic acids (mono-, di- and tri-) at a C60-[dimethyl-(beta-cyclodextrin)]2 and nafion chemically modified electrode.
MedLine Citation:
PMID:  18968196     Owner:  NLM     Status:  PubMed-not-MEDLINE    
The C(60)-[dimethyl-(beta-cyclodextrin)](2) and nafion chemically modified electrode (CME) exhibits one electroreduction peak and two electro-oxidation peaks in a mixed solvent of water and acetonitrile (3:2, v/v) containing tetra-butylammonium perchlorate. The reduction of chloroacetic acids (mono-, di- and tri-) can be electrocatalyzed at this electrode, indicating that C(60)-[dimethyl-(beta-cyclodextrin)](2) is capable of mediating the electron transfer to chloroacetic acids. Values of the apparent catalytic rate constant, k, were determined by using the rotating-disk electrode (RDE).
M Wei; M Li; N Li; Z Gu; X Zhou
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Talanta     Volume:  53     ISSN:  1873-3573     ISO Abbreviation:  Talanta     Publication Date:  2001 Jan 
Date Detail:
Created Date:  2008-10-30     Completed Date:  2009-12-15     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2984816R     Medline TA:  Talanta     Country:  England    
Other Details:
Languages:  eng     Pagination:  1045-52     Citation Subset:  -    
Department of Chemistry, Institute of Physical Chemistry, Peking University, Beijing, People's Republic of China.
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