| Efficient Diastereoselective Synthesis of (2R,3R,4R)-2-Amino-3-hydroxy-4,5-dimethylhexanoic Acid, the Lactone Linkage Unit of Homophymine A. | |
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MedLine Citation:
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PMID: 23370199 Owner: NLM Status: In-Data-Review |
Abstract/OtherAbstract:
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For the total synthesis of novel cyclodepsipeptide homophymine A, (2R,3R,4R)-2-amino-3-hydroxy-4,5-dimethylhexanoic acid was successfully synthesized by Evans' asymmetric alkylation and the anti-selective asymmetric hydrogenation of a chiral α-amino-β-keto ester as the key steps. |
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Authors:
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Junpei Ohtaka; Akinari Hamajima; Tetsuhiro Nemoto; Yasumasa Hamada |
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Publication Detail:
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Type: Journal Article |
Journal Detail:
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Title: Chemical & pharmaceutical bulletin Volume: 61 ISSN: 1347-5223 ISO Abbreviation: Chem. Pharm. Bull. Publication Date: 2013 |
Date Detail:
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Created Date: 2013-02-01 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0377775 Medline TA: Chem Pharm Bull (Tokyo) Country: Japan |
Other Details:
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Languages: eng Pagination: 245-50 Citation Subset: IM |
Affiliation:
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Graduate School of Pharmaceutical Sciences, Chiba University. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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