Document Detail

Effective macroion-macroion potentials in asymmetric electrolytes.
MedLine Citation:
PMID:  11308458     Owner:  NLM     Status:  MEDLINE    
Effective macroion-macroion potentials in solutions of macroions carrying 60 elementary charges and either monovalent or divalent counterions have been calculated at different concentrations by means of Monte Carlo simulations with a consequent inversion of radial distribution functions according to Lyubartsev and Laaksonen [Phys. Rev. E 52, 3730 (1995)]. With monovalent counterions, the effective potentials are essentially of a Yukawa type, whereas with divalent ones, an attractive region appears at short separation. A charge renormalization scheme invoking the cell model and the assumption of a Yukawa-type potential works favorably only in the case of monovalent counterions.
V Lobaskin; A Lyubartsev; P Linse
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Publication Detail:
Type:  Journal Article     Date:  2001-01-09
Journal Detail:
Title:  Physical review. E, Statistical, nonlinear, and soft matter physics     Volume:  63     ISSN:  1539-3755     ISO Abbreviation:  Phys Rev E Stat Nonlin Soft Matter Phys     Publication Date:  2001 Feb 
Date Detail:
Created Date:  2001-04-19     Completed Date:  2004-02-23     Revised Date:  2008-11-21    
Medline Journal Info:
Nlm Unique ID:  101136452     Medline TA:  Phys Rev E Stat Nonlin Soft Matter Phys     Country:  United States    
Other Details:
Languages:  eng     Pagination:  020401     Citation Subset:  IM    
Soft Condensed Matter Group, Institute of Physics, University of Fribourg, CH-1700 Fribourg, Switzerland.
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MeSH Terms
Biophysical Phenomena
Electrolytes / chemistry*
Monte Carlo Method
Reg. No./Substance:
0/Electrolytes; 0/Ions

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