| Effect of oxidant type on the chemiluminescence intensity from the reaction of tris(2,2'-bipyridyl)ruthenium(III) with various organic acids. | |
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MedLine Citation:
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PMID: 19071656 Owner: NLM Status: In-Data-Review |
Abstract/OtherAbstract:
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An investigation into the chemiluminescence of fourteen organic acids and tris(2,2'-bipyridyl)ruthenium(II) was undertaken. Particular emphasis was placed upon the method of production of the reagent, tris(2,2'-bipyridyl)ruthenium(III), with cerium(IV) sulfate, potassium permanganate, lead dioxide and electrochemical generation. Analytically useful chemiluminescence was observed when Ce(IV) or potassium permanganate were employed as oxidants. The kinetics of analyte oxidation was related to the intensity of the chemiluminescence emission, which increased by three orders of magnitude for tartaric acid after 40h of oxidation. |
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Authors:
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Bree A Gorman; Kieran F Lim; Conor F Hogan; Neil W Barnett |
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Publication Detail:
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Type: Journal Article Date: 2006-12-27 |
Journal Detail:
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Title: Talanta Volume: 72 ISSN: 1873-3573 ISO Abbreviation: Talanta Publication Date: 2007 Apr |
Date Detail:
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Created Date: 2008-12-16 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 2984816R Medline TA: Talanta Country: England |
Other Details:
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Languages: eng Pagination: 568-74 Citation Subset: - |
Affiliation:
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School of Life and Environmental Sciences, Deakin University, Geelong, Victoria 3217, Australia. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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