Document Detail


Effect of oxidant type on the chemiluminescence intensity from the reaction of tris(2,2'-bipyridyl)ruthenium(III) with various organic acids.
MedLine Citation:
PMID:  19071656     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
An investigation into the chemiluminescence of fourteen organic acids and tris(2,2'-bipyridyl)ruthenium(II) was undertaken. Particular emphasis was placed upon the method of production of the reagent, tris(2,2'-bipyridyl)ruthenium(III), with cerium(IV) sulfate, potassium permanganate, lead dioxide and electrochemical generation. Analytically useful chemiluminescence was observed when Ce(IV) or potassium permanganate were employed as oxidants. The kinetics of analyte oxidation was related to the intensity of the chemiluminescence emission, which increased by three orders of magnitude for tartaric acid after 40h of oxidation.
Authors:
Bree A Gorman; Kieran F Lim; Conor F Hogan; Neil W Barnett
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Publication Detail:
Type:  Journal Article     Date:  2006-12-27
Journal Detail:
Title:  Talanta     Volume:  72     ISSN:  1873-3573     ISO Abbreviation:  Talanta     Publication Date:  2007 Apr 
Date Detail:
Created Date:  2008-12-16     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2984816R     Medline TA:  Talanta     Country:  England    
Other Details:
Languages:  eng     Pagination:  568-74     Citation Subset:  -    
Affiliation:
School of Life and Environmental Sciences, Deakin University, Geelong, Victoria 3217, Australia.
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