Document Detail


Effect of gas pressure on negative thermal expansion in MOF-5.
MedLine Citation:
PMID:  23235693     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
Powder diffraction is used to study thermal expansion properties of MOF-5 at moderate helium gas pressures: 1.7 bar (100-500 K) and 5-150 bar (150-300 K). The framework shows negative thermal expansion (NTE) at all pressures, but vibrational motions causing NTE are damped with increasing pressures, leading to decreased NTE.
Authors:
Nina Lock; Mogens Christensen; Cameron J Kepert; Bo B Iversen
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  49     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Dec 
Date Detail:
Created Date:  2012-12-19     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  England    
Other Details:
Languages:  eng     Pagination:  789-91     Citation Subset:  IM    
Affiliation:
Dept of Chemistry and iNANO, Aarhus University, DK-8000 Aarhus C, Denmark. bo@chem.au.dk.
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