| Effect of gas pressure on negative thermal expansion in MOF-5. | |
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MedLine Citation:
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PMID: 23235693 Owner: NLM Status: In-Data-Review |
Abstract/OtherAbstract:
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Powder diffraction is used to study thermal expansion properties of MOF-5 at moderate helium gas pressures: 1.7 bar (100-500 K) and 5-150 bar (150-300 K). The framework shows negative thermal expansion (NTE) at all pressures, but vibrational motions causing NTE are damped with increasing pressures, leading to decreased NTE. |
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Authors:
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Nina Lock; Mogens Christensen; Cameron J Kepert; Bo B Iversen |
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Publication Detail:
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Type: Journal Article |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: 49 ISSN: 1364-548X ISO Abbreviation: Chem. Commun. (Camb.) Publication Date: 2012 Dec |
Date Detail:
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Created Date: 2012-12-19 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: England |
Other Details:
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Languages: eng Pagination: 789-91 Citation Subset: IM |
Affiliation:
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Dept of Chemistry and iNANO, Aarhus University, DK-8000 Aarhus C, Denmark. bo@chem.au.dk. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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