Document Detail


Dynamic symmetry breaking in a model of polymer reptation.
MedLine Citation:
PMID:  8832165     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
A numerical study of the transition between oriented and nonoriented polymers in a model for reptation is presented. An electric field biases a charged polymer to drift in the direction of its leading end. At low fields this bias is not enough to orient the polymer, but at larger fields it succeeds in orienting the polymer with a definite head and tail. The resulting motion depends on the relative magnitudes of the field and the chain length. For a given chain length, the field plays the role of inverse temperature in this transition. The critical field between these "phases" is found to be a non-trivial power of the length of the chain. This scaling extends over two full decades in the coupling parameter and the simulations performed involved 2 x 10(9) Monte Carlo steps per data point.
Authors:
D P Aalberts; J M van Leeuwen
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Electrophoresis     Volume:  17     ISSN:  0173-0835     ISO Abbreviation:  Electrophoresis     Publication Date:  1996 Jun 
Date Detail:
Created Date:  1996-12-11     Completed Date:  1996-12-11     Revised Date:  2006-11-15    
Medline Journal Info:
Nlm Unique ID:  8204476     Medline TA:  Electrophoresis     Country:  GERMANY    
Other Details:
Languages:  eng     Pagination:  1003-10     Citation Subset:  IM    
Affiliation:
Instituut Lorentz for Theoretical Physics, University of Leiden, The Netherlands. aalberts@lorentz.leidenuniv.nl
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MeSH Terms
Descriptor/Qualifier:
Computer Simulation*
Electrophoresis*
Models, Molecular*
Numerical Analysis, Computer-Assisted*
Polymers / chemistry*
Chemical
Reg. No./Substance:
0/Polymers

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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