Document Detail


Dual patterning and sequential functionalization of block copolymers using photocrosslinkable random copolymer film.
MedLine Citation:
PMID:  19546495     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
A novel method of dual patterning and sequential functionalization of block copolymers is proposed using a photocrosslinkable random copolymer film, poly(styrene-r-(tert-butyl acrylate)-r-(cinnamoyloxyethyl acrylate)). The tert-butyl esters of the block copolymer, polystyrene-block-poly(tert-butyl acrylate), coated on the patterned random copolymer film were sequentially deprotected to give carboxylic acids using an acid catalyst and heat treatment. The sequentially produced carboxylic acid patterns were used for the sequential patterning of gold nanoparticles as an example of potential applications.
Authors:
Se Jin Ku; Su Min Kim; Jin-Baek Kim
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't     Date:  2009-06-23
Journal Detail:
Title:  Nanotechnology     Volume:  20     ISSN:  1361-6528     ISO Abbreviation:  Nanotechnology     Publication Date:  2009 Jul 
Date Detail:
Created Date:  2009-06-24     Completed Date:  2009-08-25     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101241272     Medline TA:  Nanotechnology     Country:  England    
Other Details:
Languages:  eng     Pagination:  285304     Citation Subset:  IM    
Affiliation:
Department of Chemistry and School of Molecular Science (BK21), Korea Advanced Institute of Science and Technology (KAIST), Yuseong-Gu, Daejeon, Republic of Korea.
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MeSH Terms
Descriptor/Qualifier:
Acrylates / chemistry*
Nanoparticles / chemistry*
Photochemistry / methods*
Polymers / chemical synthesis*,  chemistry*
Polystyrenes / chemistry*
Chemical
Reg. No./Substance:
0/Acrylates; 0/Polymers; 0/Polystyrenes; 0/poly(styrene-b-tert-butylacrylate); 0/tert-butyl acrylate

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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